14264-32-5

Basic information

• Product Name: Ni(trifluorophosphine)(CO)3
• Synonyms: Ni(trifluorophosphine)(CO)3
• CAS NO: 14264-32-5
• Molecular Weight: 230.69
• Mol File: 14264-32-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ni(trifluorophosphine)(CO)3(CAS DataBase Reference)
• NIST Chemistry Reference: Ni(trifluorophosphine)(CO)3(14264-32-5)
• EPA Substance Registry System: Ni(trifluorophosphine)(CO)3(14264-32-5)

Safety Data

• Hazardous Substances Data: 14264-32-5(Hazardous Substances Data)

Upstream product

• 13463-39-3 tetracarbonyl nickel 
• 7783-55-3 trifluorophosphane 

Downstream Products

• 13859-65-9 tetrakis(trifluorophosphine)nickel 
• 13463-39-3 tetracarbonyl nickel 

Relevant articles and documents

Trifluorophosphine complexes of nickel

Mixtures of the Ni(CO)x(PF3)4-x compounds can best be prepared by either the interaction of Ni(CO)4 and Ni(PF3)4 at about 70° or the reaction between PF3 and Ni(CO)4 at 100° in a pressure vessel. The presence of finely divided nickel metal in the latter approach increases the yield. The composition of the mixtures represents a nearly random arrangement of ligands among the various species. The pure compounds, isolated by means of vapor phase chromatography, have physical properties quite similar to those of the parent compounds and infrared and nuclear magnetic resonance studies clearly pointout the very great similarity between CO and PF3 as ligands.