142683-15-6

Basic information

• Product Name: Triisopropyl-(6-phenyl-cyclohex-1-enyloxy)-silane
• Synonyms: Triisopropyl-(6-phenyl-cyclohex-1-enyloxy)-silane
• CAS NO: 142683-15-6
• Molecular Weight: 330.586
• Mol File: 142683-15-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Triisopropyl-(6-phenyl-cyclohex-1-enyloxy)-silane(CAS DataBase Reference)
• NIST Chemistry Reference: Triisopropyl-(6-phenyl-cyclohex-1-enyloxy)-silane(142683-15-6)
• EPA Substance Registry System: Triisopropyl-(6-phenyl-cyclohex-1-enyloxy)-silane(142683-15-6)

Safety Data

• Hazardous Substances Data: 142683-15-6(Hazardous Substances Data)

Upstream product

• 1444-65-1 (RS)-2-phenylcyclohexanone 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 

Downstream Products

• 142683-13-4 2-phenyl-1-(tri(isopropyl)silyloxy)cyclohex-1-ene 
• 36702-38-2 5,6-dihydro-[1,1'-biphenyl]-2(1H)-one 

Relevant articles and documents

Method for the Direct Enantioselective Synthesis of Chiral Primary α-Amino Ketones by Catalytic α-Amination

A useful catalytic enantioselective approach has been developed for the synthesis of chiral ketamine analogs using Rh(II)-catalyzed amination of triisopropylsilyl enol ethers to form α-amino ketones with O-(4-nitrophenyl)hydroxylamine as nitrogen donor in 81-91% ee.