14271-99-9Relevant articles and documents
Palladium-Catalyzed Silylation of Aryl Chlorides with Bulky Dialkoxydisilanes
Fukui, Keitaro,Saito, Hayate,Shimokawa, Jun,Yorimitsu, Hideki
, p. 1328 - 1332 (2020)
Arylsilanes bearing a bulky alkoxy group on the silicon were synthesized from aryl chlorides and dialkoxydisilanes under reaction conditions utilizing SingaCycle-A3 as a palladium precatalyst and lithium benzoate in wet DMA. This report proposes the first direct and catalytic method for introducing tert -butoxy- or 1-adamantyloxysilyl groups onto various aryl moieties through the silylation reaction.
Synthesis and Structure of New Polymeric Lithium Pivalates
Bazhina, E. S.,Eremenko, I. L.,Gogoleva, N. V.,Kiskin, M. A.,Lutsenko, I. A.,Nikolaevskii, S. A.,Sidorov, A. A.,Yambulatov, D. S.,Zorina-Tikhonova, E. N.
, (2020)
Abstract: Data on the synthesis and study of the crystal structure of [Li10(Piv)10(MeCN)2]n (I) and [Li6(Piv)6(MeCN)2]n (II) are presented. According to X-ray diffract
Thermodynamic Characteristics of Lithium Pivalate according to High-Temperature Mass Spectrometry Data
Alikhanyan, A. S.,Kayumova, D. B.,Kiskin, M. A.,Malkerova, I. P.
, p. 868 - 873 (2021/07/30)
Abstract: The vaporization of lithium pivalate (CH3)3CCOOLi (LiPiv) was studied by the Knudsen effusion method with the mass spectral analysis of the gas phase. The saturated vapor consisted of polynuclear molecules (LiPiv)n/su