1427465-29-9

Basic information

• Product Name: 1-(4-methylphenyl)-1H-1λ³-benzo[b]iodo-3(2H)-one
• Synonyms: 1-(4-methylphenyl)-1H-1λ³-benzo[b]iodo-3(2H)-one
• CAS NO: 1427465-29-9
• Molecular Weight: 338.145
• Mol File: 1427465-29-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(4-methylphenyl)-1H-1λ³-benzo[b]iodo-3(2H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-methylphenyl)-1H-1λ³-benzo[b]iodo-3(2H)-one(1427465-29-9)
• EPA Substance Registry System: 1-(4-methylphenyl)-1H-1λ³-benzo[b]iodo-3(2H)-one(1427465-29-9)

Safety Data

• Hazardous Substances Data: 1427465-29-9(Hazardous Substances Data)

Upstream product

• 88-67-5 2-Iodobenzoic acid 
• 108-88-3 toluene 

Downstream Products

• 31162-13-7 2-azidobenzoic acid 

Relevant articles and documents

Synthesis of arylbenziodoxoles using pseudocyclic benziodoxole triflate and arenes

An acid activated pseudocyclic hypervalent iodine reagent, 2-[hydroxy(trifluoromethanesufonyloxy)]-iodobenzoic acid, can easily react with various arenes in the presence of trifluoromethanesulfonic acid to produce pseudocyclic diaryliodonium triflate salt

Preparation and X-ray structural study of 1-arylbenziodoxolones

Various 1-arylbenziodoxolones can be conveniently prepared from 2-iodobenzoic acid and arenes by a one-pot procedure using Oxone (2KHSO 5·KHSO4·K2SO4) as an inexpensive and environmentally safe oxidant. This procedure is also applicable for the synthesis of the 7-methylbenziodoxolone ring system using 2-iodo-3-methylbenzoic acid as starting compound. Structures of four 1-arylbenziodoxolone derivatives were established by single-crystal X-ray diffraction analysis. An enhanced reactivity of 1-aryl-7-methylbenziodoxolones toward nucleophiles compared to unsubstituted 1-arylbenziodoxolones has been found.