142807-63-4Relevant articles and documents
Amorphous molecular materials with high carrier mobilities: Thiophene- and selenophene-containing tris(oligoarylenyl)amines
Ohishi, Hitoshi,Tanaka, Masatake,Kageyama, Hiroshi,Shirota, Yasuhiko
, p. 1266 - 1267 (2004)
A novel class of amorphous molecular materials, thiophene-and selenophene-containing tris(oligoarylenyl)amines, were developed. They were found to exhibit high hole drift mobilities greater than 10-2 cm 2V-1s-1 at an electric field of 1.0 × 105 Vcm-1 at 293 K in their amorphous glassy states. These values are of the highest level among those reported for organic disordered systems.
Triphenylamine-thienylenevinylene hybrid systems with internal charge transfer as donor materials for heterojunction solar cells
Roquet, Sophie,Cravino, Antonio,Leriche, Philippe,Aleveque, Olivier,Frere, Pierre,Roncali, Jean
, p. 3459 - 3466 (2006)
Star-shaped molecules based on a triphenylamine core derivatized with various combinations of thienylenevinylene conjugated branches and electron-withdrawing indanedione or dicyanovinyl groups have been synthesized. UV-vis absorption and fluorescence emis
Electrochromic properties of organic-inorganic composite materials
Liu, Weishi,Zhang, Xiaoyuan,Liu, Jianqiang,Ma, Xiaodan,Zeng, Jinming,Liu, Ping,Xu, Tiangui
, p. 379 - 385 (2017)
A new type of electroactive composite material based on tungsten trioxide (WO3) and poly (tri(4-(2′-thienyl)) phenylamine) (P3TPA) was prepared. Using the WO3/P3TPA as electroactive material, the electrochromic device was fabricated,
Di(p-methoxyphenyl)amine end-capped tri(p-thiophenylphenyl)amine based molecular glasses as hole transporting materials for solid-state dye-sensitized solar cells
Bui, Thanh-Tuan,Shah, Said Karim,Sallenave, Xavier,Abbas, Mamatimin,Sini, Gjergji,Hirsch, Lionel,Goubard, Fabrice
, p. 49590 - 49597 (2015)
Three tris(thienylphenyl)amine-based molecular glass hole transporting materials were synthetized, characterized and incorporated in solid state dye-sensitized solar cells. Devices using these compounds as solid hole conductors show relatively high V
Facile one-pot nanocatalysts encapsulation of palladium-NHC complexes for aqueous Suzuki-Miyaura couplings
Chen, Chao,Zheng, Qing,Ni, Shengliang,Wang, Hangxiang
, p. 4624 - 4630 (2018/03/21)
Organic transformations using water as the solvent have been the focus of intense investigation. We herein present a strategy that uses simple nanoparticle encapsulation to fabricate water-soluble nanocatalysts (NCs) for aqueous cross-coupling reactions. To achieve this goal, three types of N-heterocyclic carbene (NHC)-palladium (Pd) complexes (i.e., 1b, 2b, and 3b) with the chemical formula [PdL(CH3CN)Cl]PF6 (where L is a bidentate pyridine- or pyrimidine-bearing NHC ligand) have been synthesized, and their structures were characterized by NMR spectroscopy and X-ray crystallography. Exploiting a facile one-pot encapsulation process, the water-insoluble Pd-NHC complexes can be integrated into the hydrophobic cores of micelles composed of an amphiphilic copolymer. These water-dispersed nanoparticles exhibited excellent catalytic activity in aqueous Suzuki-Miyaura couplings. Among these NCs, 3b-NC, bearing a mesityl moiety on its NHC ligand, was found to be the most active catalyst under the tested reaction conditions. More impressively, 3b-NC can be reused for at least five cycles without substantial loss of catalytic activity.
Electrochromic properties of polymers/copolymers via electrochemical polymerization based on star-shaped thiophene derivatives with different central cores
Li, Weijun,Chen, Lan,Pan, Yuyu,Yan, Shuanma,Dai, Yuyu,Liu, Jin,Yu, Yue,Qu, Xingxing,Song, Qingbao,Ouyang, Mi,Zhang, Cheng
, p. E84 - E89 (2017/06/19)
Three star-shaped thiophene derivatives, namely TPAT, PHT and TPTT with different central cores of triphenylamine, phenyl and 2,4,6-triphenyl-1,3,5-triazine respectively, were synthesized and characterized. They were further successfully prepared into the