1428647-00-0

Basic information

• Product Name: (R,E)-methyl 4-oxo-4-(2-oxo-4-phenyloxazolidin-3-yl)but-2-enoate
• Synonyms: (R,E)-methyl 4-oxo-4-(2-oxo-4-phenyloxazolidin-3-yl)but-2-enoate
• CAS NO: 1428647-00-0
• Molecular Weight: 275.261
• Mol File: 1428647-00-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R,E)-methyl 4-oxo-4-(2-oxo-4-phenyloxazolidin-3-yl)but-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: (R,E)-methyl 4-oxo-4-(2-oxo-4-phenyloxazolidin-3-yl)but-2-enoate(1428647-00-0)
• EPA Substance Registry System: (R,E)-methyl 4-oxo-4-(2-oxo-4-phenyloxazolidin-3-yl)but-2-enoate(1428647-00-0)

Safety Data

• Hazardous Substances Data: 1428647-00-0(Hazardous Substances Data)

Upstream product

• 2756-87-8 methyl hydrogen fumarate 
• 90319-52-1 (4R)-phenyl-2-oxazolidinone 

Downstream Products

• 851960-34-4 ?(R)-methyl 4-oxo-4-((R)-2-oxo-4-phenyloxazolidin-3-yl)-2-phenylbutanoate 
• 1428647-07-7 (R)-3-((2S,3R,4S)-4-methyl-5-oxo-2-tridecyltetrahydrofuran-3-carbonyl)-4-phenyloxazolidin-2-one 
• 1428647-01-1 (S)-methyl 2-methyl-4-oxo-4-((R)-2-oxo-4-phenyloxazolidin-3-yl)butanoate 
• 1428647-02-2 (S)-methyl 2-ethyl-4-oxo-4-((R)-2-oxo-4-phenyloxazolidin-3-yl)butanoate 
• 1428647-03-3 (S)-methyl 2-(2-oxo-2-((R)-2-oxo-4-phenyloxazolidin-3-yl)ethyl)hexanoate 

Relevant articles and documents

Total synthesis of (-)-dihydroprotolichesterenic acid via diastereoselective conjugate addition to a chiral fumarate

A diastereoselective conjugate addition of a variety of monoorganocuprates, Li[RCuI], to chiral fumarates to provide funtionalized succinates has been developed. The utility of this reaction is demonstrated in a concise total synthesis of (-)-dihydroprotolichesterenic acid that required only four steps and proceeded in an overall 31% yield.