1430073-48-5

Basic information

• Product Name: C₃₆H₄₀Cl₄N₂W
• Synonyms: C₃₆H₄₀Cl₄N₂W
• CAS NO: 1430073-48-5
• Molecular Weight: 826.389
• Mol File: 1430073-48-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₆H₄₀Cl₄N₂W(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₆H₄₀Cl₄N₂W(1430073-48-5)
• EPA Substance Registry System: C₃₆H₄₀Cl₄N₂W(1430073-48-5)

Safety Data

• Hazardous Substances Data: 1430073-48-5(Hazardous Substances Data)

Upstream product

• 13283-01-7 tungsten(VI) chloride 

Relevant articles and documents

Salt-free reducing reagent of bis(trimethylsilyl)cyclohexadiene mediates multielectron reduction of chloride complexes of W(VI) and W(IV)

We developed a salt-free reduction of WCl6 using 1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene (MBTCD) in toluene to give a low-valent trinulcear tungsten complex involving W(II) and W(III) centers, while in the presence of redox active ligands such as α-diketone and α-diimine the same reduction produced W(IV) complexes with the corresponding redox-active ligands, (α-diketone)WCl4 and (α-diimine)WCl4. A W(VI) complex with two α-diketone ligands, (α-diketone)2WCl2, was found to be synthetically equivalent to low-valent W(IV) species that trapped azopyridine to give (α-diketone)WCl2(azopyridine).