1430102-37-6

Basic information

• Product Name: 1-(2,2-dibromoethenyl)-3-(trifluoromethyl)benzene
• Synonyms: 1-(2,2-dibromoethenyl)-3-(trifluoromethyl)benzene
• CAS NO: 1430102-37-6
• Molecular Weight: 329.942
• Mol File: 1430102-37-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(2,2-dibromoethenyl)-3-(trifluoromethyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2,2-dibromoethenyl)-3-(trifluoromethyl)benzene(1430102-37-6)
• EPA Substance Registry System: 1-(2,2-dibromoethenyl)-3-(trifluoromethyl)benzene(1430102-37-6)

Safety Data

• Hazardous Substances Data: 1430102-37-6(Hazardous Substances Data)

Upstream product

• 558-13-4 carbon tetrabromide 
• 454-89-7 3-Trifluoromethylbenzaldehyde 

Downstream Products

• 351-35-9 3-(trifluoromethyl)phenylacetic acid 
• 1430102-68-3 1,2-diphenyl-5-(3-(trifluoromethyl)phenyl)-1H-pyrrole 
• 1430102-42-3 1-(phenylbuta-1,3-diyn-1-yl)-3-(trifluoromethyl)benzene 

Relevant articles and documents

Synthesis of Chiral Propargylamines, Chiral 1,2-Dihydronaphtho[2,1-b]furans and Naphtho[2,1-b]furans with C-Alkynyl N,N′-di-(tert-butoxycarbonyl)-aminals and β-Naphthols

Chiral phosphoric acid-catalyzed couplings of C-alkynyl N,N′-di-(tert-butoxycarbonyl)-aminals with β-naphthols led to chiral propargylamines in moderate to high yields with high to excellent enantioselectivity, in which the reactions underwent sequential chiral phosphoric acid-catalyzed in situ formation of N-(tert-butoxycarbonyl)-imines (N-Boc-imines) from the aminals, and 1,2-addition of β-naphthols to the N-Boc-imines. Chiral 1,2-dihydronaphtho[2,1-b]furans and naphtho[2,1-b]furans were prepared with satisfactory results when 10 mol% AgOAc and 20 mol% 2,6-lutidine or 1.2 equiv. of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) were added to the resulting chiral propargylamines solution, respectively.