143037-14-3

Basic information

• Product Name: AlCl(OC₆H₂(C(CH₃)3)2CH₃)2(O(C₂H₅)2)
• CAS NO: 143037-14-3
• Molecular Weight: 575.251
• Mol File: 143037-14-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: AlCl(OC₆H₂(C(CH₃)3)2CH₃)2(O(C₂H₅)2)(CAS DataBase Reference)
• NIST Chemistry Reference: AlCl(OC₆H₂(C(CH₃)3)2CH₃)2(O(C₂H₅)2)(143037-14-3)
• EPA Substance Registry System: AlCl(OC₆H₂(C(CH₃)3)2CH₃)2(O(C₂H₅)2)(143037-14-3)

Safety Data

• Hazardous Substances Data: 143037-14-3(Hazardous Substances Data)

Upstream product

• 61986-88-7 aluminum(ethyl)(2,6-di-tert-butyl-4-methylphenoxy)2 
• 60-29-7 diethyl ether 
• 10025-82-8 indium(III) chloride 
• 1066-45-1 trimethyltin(IV)chloride 
• 56252-57-4 isobutylbis(3,5-di-tert-butyl-4-hydroxytoluene)aluminum 
• 56252-55-2 bis(2,6-di-tert-butyl-4-methylphenoxide)methylaluminum 

Relevant articles and documents

Synthesis and properties of homogeneous models of the Re2O7/Al2O3 metathesis catalyst

Soluble complexes, including aluminum coordinated with a perrhenate and a 4-substituted-2-6-di-tert-butylphenoxy ligand or a CH2- or S-ortho bridged-4,4'-di-tert-butyldiphenoxy ligand, were synthesized and characterized. The reaction of (ArO)2Al-Cl with AgReO4 resulted in new complexes (ArO)2Al-OReO3 (A), which showed a low activity in the metathesis of 2-pentene. Complexes (ArO)2Al-R (R = isobutyl, ethyl) reacted with Re2O7 in tetrahydrofuran or dioxane, generating type B complexes including oligomeric linkages such as O3Re-[Al(OAr)-O]2-ReO3. Some of these complexes, unstable even under an argon atmosphere, were identified after stabilization with a Lewis base like quinuclidine or bipyridine. Before their stabilization, they exhibited a rather high activity in the metathesis of 2-pentene, with turnover frequency of 100/min, and functional olefins (diallylether, diallylsulfide). Upon reaction with (ArO)2Al-R in an ether solvent, A complexes might be converted into B complexes. The high activity of B complexes was associated with the presence of Al-O-Al linkages that are known to induce a powerful bidendate Lewis acidity.