1430737-67-9

Basic information

• Product Name: C₄₆H₃₂F₄N₄O₈P₂
• Synonyms: C₄₆H₃₂F₄N₄O₈P₂
• CAS NO: 1430737-67-9
• Molecular Weight: 906.723
• Mol File: 1430737-67-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₄₆H₃₂F₄N₄O₈P₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₄₆H₃₂F₄N₄O₈P₂(1430737-67-9)
• EPA Substance Registry System: C₄₆H₃₂F₄N₄O₈P₂(1430737-67-9)

Safety Data

• Hazardous Substances Data: 1430737-67-9(Hazardous Substances Data)

Upstream product

• 1430737-64-6 C₄₆H₃₆N₄O₁₂P₂ 

Downstream Products

• 1610459-21-6 C₈₂H₁₂₀N₈O₂₀P₂Si₄ 

Relevant articles and documents

Immobilized bisdiazaphospholane catalysts for asymmetric hydroformylation

Condensation reactions of enantiopure bis-3,4-diazaphospholanes (BDPs) that are functionalized with carboxylic acids enable covalent attachment to bead and silica supports. Exposure of tethered BDPs to the hydroformylation catalyst precursor, Rh(acac)(CO)2, yields catalysts for immobilized asymmetric hydroformylation (iAHF) of prochiral alkenes. Compared with homogeneous catalysts, catalysts immobilized on Tentagel resins exhibit similarly high regioselectivity and enantioselectivity. When corrected for apparent catalyst loading, the activity of the immobilized catalysts approaches that of the homogeneous analogues. Excellent recyclability with trace levels of rhodium leaching are observed in batch and flow reactor conditions. Silica-bound catalysts exhibit poorer enantioselectivities.