1430885-79-2

Basic information

• Product Name: tert-butyl 3-(diphenylphosphino)-1H-indole-1-carboxylate
• Synonyms: tert-butyl 3-(diphenylphosphino)-1H-indole-1-carboxylate
• CAS NO: 1430885-79-2
• Molecular Weight: 401.445
• Mol File: 1430885-79-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tert-butyl 3-(diphenylphosphino)-1H-indole-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl 3-(diphenylphosphino)-1H-indole-1-carboxylate(1430885-79-2)
• EPA Substance Registry System: tert-butyl 3-(diphenylphosphino)-1H-indole-1-carboxylate(1430885-79-2)

Safety Data

• Hazardous Substances Data: 1430885-79-2(Hazardous Substances Data)

Upstream product

• 153942-69-9 3-bromo-1-(tert-butyl-dimethyl-silanyl)-1H-indole 
• 40899-73-8 N-tert-butyldimethylsilylindole 
• 120-72-9 indole 
• 24424-99-5 di-tert-butyl dicarbonate 
• 1430885-75-8 3-(diphenylphosphino)-1H-indole 
• 1430885-74-7 1-(tert-butyldimethylsilyl)-3-(diphenylphosphino)-1H-indole 

Relevant articles and documents

3-Indolylphosphines as ligand for palladium in Suzuki-Miyaura coupling reaction of chloroarenes: Substituent effects

The ligand 1,3-bis(diphenylphosphino)-1H-indole, L1 with palladium promotes Suzuki-Miyaura coupling reaction of chloroarenes and benzyl chlorides with arylboronic acids. Structural modification of L1 established that the phosphine group at C-3 position of indole was crucial to catalysis and its efficacy depended on the nature of the N-substituent. 31P chemical shift values of the substituted indolylphosphines appear to show a correlation with observed trend in catalytic efficiency.