14311-00-3Relevant articles and documents
Palladium(0)-catalyzed silylation of aryl halides with triorganosilanes: Synthesis of aryl(2-furyl)silanes
Murata, Miki,Ohara, Hiroya,Oiwa, Ryo,Watanabe, Shinji,Masuda, Yuzuru
, p. 1771 - 1774 (2006)
Triorganosilanes, which possess two aryl groups on the silicon atom, undergo palladium-catalyzed silylation of aryl iodides. Aryl(2-furyl)silanes thus obtained are potentially useful starting materials for carbon-carbon bond-forming reactions in the prese
Nickel-Catalyzed Reaction of Aryl 2-Pyridyl Ethers with Silylzinc Chlorides: Silylation of Aryl 2-Pyridyl Ethers via Cleavage of the Carbon?Oxygen Bond
Kong, Ying-Ying,Wang, Zhong-Xia
supporting information, p. 5440 - 5448 (2019/11/16)
Ni-catalyzed C?O(Py) bond activation and silylation of aryl 2-pyridyl ethers with silylzinc chlorides were carried out. This protocol allowed the 2-pyridyloxy group to be substituted by a silyl group with short reaction times, mild reaction conditions, and good compatibility of functional groups. (Figure presented.).
Palladium-catalyzed silylations of hydrosilanes with aryl halides using bulky alkyl phosphine
Yamanoi, Yoshinori
, p. 9607 - 9609 (2007/10/03)
A palladium-catalyzed direct trialkylsilyl transfer to aryl halides has been developed. In the presence of Pd(t-Bu3P)2 and K 3PO4, electron-rich para- or meta-substitute aryl iodides were coupled efficiently with triethylsilane, triphenylsilane, and dimethylphenylsilane to afford the corresponding silylated products in moderate to good yields.
