143112-20-3

Basic information

• Product Name: Benzoic acid, 2-methoxy-6-(1-propenyl)-, (E)-
• CAS NO: 143112-20-3
• Molecular Formula: C11H12O3
• Molecular Weight: 192.214
• Mol File: 143112-20-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2-methoxy-6-(1-propenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2-methoxy-6-(1-propenyl)-, (E)-(143112-20-3)
• EPA Substance Registry System: Benzoic acid, 2-methoxy-6-(1-propenyl)-, (E)-(143112-20-3)

Safety Data

• Hazardous Substances Data: 143112-20-3(Hazardous Substances Data)

Upstream product

• 53015-08-0 2-formyl-6-methoxy-benzoic acid 
• 1530-32-1 ethyltriphenylphosphonium bromide 
• 579-75-9 2-Methoxybenzoic acid 
• 325172-28-9 2-allyl-6-methoxy-benzoic acid 
• 215023-79-3 2,6-di-tert-butyl-4-methoxyphenyl 2,6-dimethoxybenzoic acid ester 
• 438569-38-1 2-methoxy-6-propenyl-benzoic acid 2,6-di-tert-butyl-4-methoxy-phenyl ester 
• 30407-92-2 3,4-dihydro-8-methoxy-3-methylisocoumarin 

Downstream Products

• 438569-39-2 2-Methoxy-6-((E)-propenyl)-benzoic acid 2,6-diisopropyl-phenyl ester 
• 101445-89-0 8-benzoyloxy-3-methyl-isocoumarin 
• 438569-40-5 2',4',6'-Trimethyl-3-((E)-propenyl)-biphenyl-2-carboxylic acid 2,6-diisopropyl-phenyl ester 
• 438569-42-7 2-methyl-7-(2,4,6-trimethyl-phenyl)-inden-1-one 
• 53015-08-0 2-formyl-6-methoxy-benzoic acid 

Relevant articles and documents

Novel AlCl3 catalysed syntheses of naturally occurring (±) 8-Hydroxy-3-methyl-3,4-dihydroisocoumarins

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Catalytic C-N and C-H Bond Activation: Ortho-Allylation of Benzoic Acids with Allyl Amines

A facile insertion of ruthenium into aromatic C-H and allylic C-N bonds are the key steps in a [Ru(p-cymene)Cl2]2-catalyzed ortho-C-H allylation of benzoic acids. This protocol allows drawing on the large pool of allylic amines for state-of-the-art ortho-functionalizations of arenes, turning neutral amines into leaving groups. Concise syntheses of biologically active compounds provide further evidence of the synthetic potential of this methodology.