143158-02-5

Basic information

• Product Name: Silane, [[4-(decyloxy)phenyl]ethynyl]trimethyl-
• CAS NO: 143158-02-5
• Molecular Formula: C21H34OSi
• Molecular Weight: 330.586
• Mol File: 143158-02-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Silane, [[4-(decyloxy)phenyl]ethynyl]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [[4-(decyloxy)phenyl]ethynyl]trimethyl-(143158-02-5)
• EPA Substance Registry System: Silane, [[4-(decyloxy)phenyl]ethynyl]trimethyl-(143158-02-5)

Safety Data

• Hazardous Substances Data: 143158-02-5(Hazardous Substances Data)

Upstream product

• 30752-20-6 1-bromo-4-decyloxybenzene 
• 1066-54-2 trimethylsilylacetylene 
• 112-29-8 1-bromo dodecane 
• 106-41-2 4-bromo-phenol 

Downstream Products

• 1065644-39-4 2,6-bis[2-(4-decyloxyphenyl)ethynyl]anthracene 
• 115573-46-1 4-n-decyloxyphenylacetylene 
• 1400470-64-5 2,7-bis((4-(decyloxy)phenyl)ethynyl)cyclopenta[hi]-aceanthrylene 

Relevant articles and documents

Alkyloxy modified pyrene fluorophores with tunable photophysical and crystalline properties

Novel alkyloxy modified 2,7-di-tert-butyl-4,5,9,10-tetra(arylethynyl)pyrenes were prepared through a straightforward Sonogashira coupling approach. Optical properties such as quantum yields and absorption/emission spectra of the fluorophores were investigated by UV/Vis and fluorescence measurements. Aggregation induced excimer formation of the chromophores in polar solvents and in the solid state was proved by the presence of a characteristic bathochromically shifted emission band and a decrease of the emission capability. These results strongly indicate the unexpected observation that the excimer formation of adjacent pyrene rings is not prevented by the introduction of bulky tert-butyl substituents. Single-crystal X-ray and computational analyses reveal the co-planar alignment of adjacent molecules and the presence of π-π-stacking in the molecular packing of the pyrene polyaromatics. Furthermore, fluorescence, DSC and POM measurements indicate that the aggregation behaviour, the thermal characteristics and the crystalline properties are significantly influenced by changing structural features of the attached functional groups at the periphery of the pyrene core.

Solution processable symmetric 4-alkylethynylbenzene end-capped anthracene derivatives

New candidates composed of anthracene and 4-alkylethynylbenzene end-capped oligomers for OTFTs were synthesized under Sonogashira coupling reaction conditions. All oligomers were characterized by FT-IR, mass, UV-visible, and PL emission spectrum analyses, cyclic voltammetry (CV), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), 1H-NMR, and 13C-NMR. Investigation of their physical properties showed that the oligomers had high oxidation potential and thermal stability. Thin films of DHPEAnt and DDPEAnt were characterized by spin coating them onto Si/SiO 2 to fabricate top-contact OTFTs. The devices prepared using DHPEAnt and DDPEAnt showed hole field-effect mobilities of 4.0 × 10-3 cm2/Vs and 2.0 × 10-3 cm2/Vs, respectively, for solution-processed OTFTs.