143283-95-8

Basic information

• Product Name: 1,2-Cyclohexanediamine, N,N'-bis(2-furanylmethylene)-
• CAS NO: 143283-95-8
• Molecular Formula: C16H18N2O2
• Molecular Weight: 270.331
• Mol File: 143283-95-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2-Cyclohexanediamine, N,N'-bis(2-furanylmethylene)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Cyclohexanediamine, N,N'-bis(2-furanylmethylene)-(143283-95-8)
• EPA Substance Registry System: 1,2-Cyclohexanediamine, N,N'-bis(2-furanylmethylene)-(143283-95-8)

Safety Data

• Hazardous Substances Data: 143283-95-8(Hazardous Substances Data)

Upstream product

• 98-01-1 furfural 
• 1121-22-8 trans-1,2-Diaminocyclohexane 

Relevant articles and documents

Cyanide-Catalyzed Cyclizations via Aldimine Coupling

Aldimine coupling (AIC) is the nitrogen analogue of the benzoin condensation and has been applied to dialdimines, providing the first examples of cyclizations effected by cyanide-catalyzed AIC. Sodium cyanide promoted the facile, intramolecular cyclization of several dialdimines in N,N-dimethylformamide, methanol, or methylene chloride/water (phase-transfer conditions) yielding a variety of six-membered heterocycles. Under aerobic conditions, an oxidative cyclization occurs to provide the diimine heterocycle. Oligomerization was observed with rigid dialdimines for which cyclization was precluded.