14337-77-0

Basic information

• Product Name: Phosphinic acid, dimethyl-, methyl ester
• CAS NO: 14337-77-0
• Molecular Formula: C3H9O2P
• Molecular Weight: 108.077
• Mol File: 14337-77-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Phosphinic acid, dimethyl-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphinic acid, dimethyl-, methyl ester(14337-77-0)
• EPA Substance Registry System: Phosphinic acid, dimethyl-, methyl ester(14337-77-0)

Safety Data

• Hazardous Substances Data: 14337-77-0(Hazardous Substances Data)

Upstream product

• 29952-66-7 methyl dimethylphosphinothionate 
• 594-09-2 trimethylphosphane 
• 67-56-1 methanol 
• 80918-98-5 N-(2-phenylethyl)-P,P-dimethylphosphinamide 

Downstream Products

• 1070-93-5 dimethyl diphosphonic acid dimethyl ester 
• 100-52-7 benzaldehyde 
• 3283-12-3 dimethylphosphinic acid 

Relevant articles and documents

The Acid-catalysed Hydrolysis of O-Methyl Dimethylthiophosphinate. Direct Evidence for Pentaco-ordinate Intermediate Formation in the Conversion of the P=S Ester into the P=O Ester

Hydrolysis of the title compound in strong acid leads not only to the phosphinic acid but also to methyl dimethylphosphinate which could only be formed by the intermediacy of a pentaco-ordinate species.

POSSIBLE EVIDENCE FOR A NEW MECHANISM FOR REACTION OF TRIMETHYLPHOSPHINE WITH DIOXYGEN

Evidence is presented suggesting that the mechanism for reaction of thrimethylphosphine with dioxygen proceeds through Me3PO2 as an intermediate.A mechanistic scheme is proposed to explain the products observed and the spectroscopic data obtained.