1434169-86-4

Basic information

• Product Name: [(pentamethylcyclopentadiene)(PMe₃)IrBn₂]
• Synonyms: [(pentamethylcyclopentadiene)(PMe₃)IrBn₂]
• CAS NO: 1434169-86-4
• Molecular Weight: 585.792
• Mol File: 1434169-86-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(pentamethylcyclopentadiene)(PMe₃)IrBn₂](CAS DataBase Reference)
• NIST Chemistry Reference: [(pentamethylcyclopentadiene)(PMe₃)IrBn₂](1434169-86-4)
• EPA Substance Registry System: [(pentamethylcyclopentadiene)(PMe₃)IrBn₂](1434169-86-4)

Safety Data

• Hazardous Substances Data: 1434169-86-4(Hazardous Substances Data)

Upstream product

• 6921-34-2 benzylmagnesium chloride 

Downstream Products

• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 1434169-88-6 [(pentamethylcyclopentadiene)(PMe₃)Ir(Bn)Cl] 
• 148978-28-3 [(1,5-cyclooctadiene)Pt(Me)Bn] 
• 1434169-91-1 [(pentamethylcyclopentadiene)(PMe₃)Ir(Bn)(OAc)] 
• 101-81-5 Diphenylmethane 
• 620-83-7 1-methyl-4-(phenylmethyl)benzene 
• 713-36-0 2-benzyltoluene 
• 620-95-1 3-benzylpyridine 
• 613-59-2 2-benzylnaphthalene 
• 23450-30-8 methyl 4-benzylbenzoate 
• 34239-04-8 1-benzyl-4-(trifluoromethyl)benzene 
• 834-14-0 p-benzylanizole 
• 1434169-94-4 [(pentamethylcyclopentadiene)(PMe₃)Ir(Bn)(TFA)] 

Relevant articles and documents

Transmetalation of alkyl ligands from Cp*(PMe3)IrR 1R2 to (cod)PtR3X

Transmetalation of alkyl and carboxylate ligands between Cp*(PMe 3)Ir complexes and d8 Pt and Pd complexes is described. Studies on the scope and kinetics of this reaction support a mechanism in which carboxylate dissociation from the Pt or Pd center precedes alkyl transfer from Ir. Subsequent reaction of the resulting Pt or Pd alkyl complex enables functionalization of the hydrocarbyl ligands and suggests new opportunities for catalytic, nondirected C-C and C-H bond functionalization reactions.