1436856-98-2

Basic information

• Product Name: (S)-4-(dimethyl(phenyl)silyl)-4,5-dihydrobenzo[b]oxepin-2(3H)-one
• CAS NO: 1436856-98-2
• Molecular Weight: 296.441
• Mol File: 1436856-98-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-4-(dimethyl(phenyl)silyl)-4,5-dihydrobenzo[b]oxepin-2(3H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-4-(dimethyl(phenyl)silyl)-4,5-dihydrobenzo[b]oxepin-2(3H)-one(1436856-98-2)
• EPA Substance Registry System: (S)-4-(dimethyl(phenyl)silyl)-4,5-dihydrobenzo[b]oxepin-2(3H)-one(1436856-98-2)

Safety Data

• Hazardous Substances Data: 1436856-98-2(Hazardous Substances Data)

Upstream product

• 25033-98-1 benzo[b]oxepin-2(5H)-one 
• 185990-03-8 dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 

Relevant articles and documents

NHC-Cu(i) catalysed asymmetric conjugate silyl transfer to unsaturated lactones: Application in kinetic resolution

The scope of the asymmetric silyl transfer to unsaturated lactones utilising a C2-symmetric NHC-Cu(i) catalyst has been established and kinetic resolutions mediated by silyl transfer have been used to prepare enantiomerically enriched anti-4,5-disubstituted 5-membered lactones. The method has been exploited in an expedient synthesis of (+)-blastmycinone.