14369-94-9Relevant articles and documents
Wehrli,Chu
, p. 3436 (1973)
Regioselective ring opening and isomerization reactions of 3,4-epoxyesters catalyzed by boron trifluoride
Izquierdo, Javier,Rodriguez, Santiago,Gonzalez, Florenci V.
, p. 3856 - 3859 (2011/09/19)
Efficient ring opening of 3,4-epoxyesters with alcohols to produce 4-alkoxy-3-hydroxyesters and their isomerization into 4-ketoesters using boron trifluoride as the catalyst are presented. Both transformations are simple and efficient methods for the synthesis of the above named synthetically useful compounds.
Polyether-substituted thiazolium ionic liquid catalysts - A thermoregulated phase-separable catalysis system for the Stetter reaction
Yu, Fengli,Zhang, Ruili,Xie, Congxia,Yu, Shitao
experimental part, p. 1196 - 1200 (2010/10/20)
A series of polyether-substituted thiazolium ionic liquids have been synthesized and used as catalysts in the Stetter reaction. The ionic liquids are a thermoregulated phase-separable catalysis (TPSC) system, because they possess the properties of critical solution temperature (CST) and inverse temperature-dependent solubility in toluene-heptane. The results showed that the novel TPSC system exhibits high recycling efficiency, and provides a potential route for a environmentally benign Stetter reaction. The Royal Society of Chemistry 2010.