1437324-90-7

Basic information

• Product Name: C₃₆H₃₁AlN₄OS
• CAS NO: 1437324-90-7
• Molecular Weight: 594.716
• Mol File: 1437324-90-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₆H₃₁AlN₄OS(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₆H₃₁AlN₄OS(1437324-90-7)
• EPA Substance Registry System: C₃₆H₃₁AlN₄OS(1437324-90-7)

Safety Data

• Hazardous Substances Data: 1437324-90-7(Hazardous Substances Data)

Upstream product

• 7446-70-0 aluminum (III) chloride 

Relevant articles and documents

Meso-thiaporphyrinoids revisited: Missing of sulfur by small metals

Facile synthesis of meso-aryl-substituted 5,15-dithiaporphyrins and 10-thiacorroles has been achieved by sulfidation of α,α'- dichlorodipyrrin metal complexes with sodium sulfide in DMF. Thiacorrole metal complexes exhibit distinct aromaticity due to 18 π-conjugation including the lone pair on sulfur, whereas dithiaporphyrins are nonaromatic judging from 1H NMR spectra, X-ray analysis, and absorption spectra. We have found that NiII and AlIII dithiaporphyrin complexes undergo smooth thermal sulfur extrusion reaction to give the corresponding thiacorrole complexes, whereas free base, ZnII, PdII, and Pt II dithiaporphyrin complexes did not exhibit the similar reactivity. The DFT calculations have elucidated a reaction pathway involving an episulfide intermediate, which can explain the markedly different reactivity among dithiaporphyrin metal complexes.