144192-55-2

Basic information

• Product Name: (1R,7aS)-1-<(p-nitrobenzoyl)oxy>-7a-methyl-7,7a-dihydro-5(6H)-indanone
• Synonyms: (1R,7aS)-1-<(p-nitrobenzoyl)oxy>-7a-methyl-7,7a-dihydro-5(6H)-indanone
• CAS NO: 144192-55-2
• Molecular Weight: 315.326
• Mol File: 144192-55-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,7aS)-1-<(p-nitrobenzoyl)oxy>-7a-methyl-7,7a-dihydro-5(6H)-indanone(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,7aS)-1-<(p-nitrobenzoyl)oxy>-7a-methyl-7,7a-dihydro-5(6H)-indanone(144192-55-2)
• EPA Substance Registry System: (1R,7aS)-1-<(p-nitrobenzoyl)oxy>-7a-methyl-7,7a-dihydro-5(6H)-indanone(144192-55-2)

Safety Data

• Hazardous Substances Data: 144192-55-2(Hazardous Substances Data)

Upstream product

• 19576-08-0 (+/-)-7a-methyl-2,3,7,7a,tetrahydro-1H-indene-1,5(6H)-dione 
• 16271-49-1 (1S,7aS)-1-hydroxy-7a-methyl-2,3,7,7a-tetrahydro-1H-inden-5(6H)-one 
• 62-23-7 4-nitro-benzoic acid 
• 99780-84-4 (7aR)-1t-hydroxy-7a-methyl-(7ar)-1,2,3,6,7,7a-hexahydro-inden-5-one 

Downstream Products

• 144299-27-4 (1R,7aS)-1-(tert-Butyl-diphenyl-silanyloxy)-7a-methyl-6-phenylselanyl-1,2,3,6,7,7a-hexahydro-inden-5-one 
• 144192-57-4 (1R,7aS)-1-(tert-butyldiphenylsiloxy)-7a-methyl-7,7a-dihydro-5(6H)-indanone 

Relevant articles and documents

Synthesis and Photochemical Rearrangement of (1R,7aS)-1-(tert-Butyldiphenylsiloxy)-7a-methyl-5(7aH)-indanone

Reaction of (1S,7aS)-1-hydroxy-7a-methyl-7,7a-dihydro-5(6H)-indanone (5a) with benzoic acid under the usual conditions of the Mitsunobu reaction gave a low yield of a 1 : 1 mixture of the benzoate derivatives 6b and 5b resulting from inversion and retenti