1443045-55-3

Basic information

• Product Name: 4,4,5,5-tetramethyl-2-(phenylthio)-1,3,2-dioxaborolane
• Synonyms: 4,4,5,5-tetramethyl-2-(phenylthio)-1,3,2-dioxaborolane
• CAS NO: 1443045-55-3
• Molecular Weight: 236.143
• Mol File: 1443045-55-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4,4,5,5-tetramethyl-2-(phenylthio)-1,3,2-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: 4,4,5,5-tetramethyl-2-(phenylthio)-1,3,2-dioxaborolane(1443045-55-3)
• EPA Substance Registry System: 4,4,5,5-tetramethyl-2-(phenylthio)-1,3,2-dioxaborolane(1443045-55-3)

Safety Data

• Hazardous Substances Data: 1443045-55-3(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 

Downstream Products

• 76200-37-8 trimethyl(1-(phenylthio)pentyl)silane 
• 90304-44-2 trimethyl(1-(phenylthio)pentadecyl)silane 
• 66080-23-7 4,4,5,5-tetramethyl-2-((phenylsulfanyl)methyl)-1,3,2-dioxaborolane 
• 76200-41-4 trimethyl(2-phenyl-1-(phenylthio)ethyl)silane 
• 128031-69-6 trimethyl(4-phenyl-1-(phenylthio)but-3-en-1-yl)silane 
• 86175-47-5 (E)-3-phenyl-3-(phenylthio)-1-(p-tolyl)prop-2-en-1-one 
• 86175-46-4 (Z)-3-phenyl-3-(phenylthio)-1-(p-tolyl)prop-2-en-1-one 

Relevant articles and documents

Frustrated Lewis Pair Catalyzed S-H Bond Borylation

The frustrated Lewis pair (FLP) [NMe2-C6H4-BH2]2 is shown to catalyze the dehydrogenative borylation of thiols. The scope of the reaction, the experimental and computational investigation of the mecha

Efficient ruthenium-catalysed S-S, S-Si and S-B bond forming reactions

[RuCl(PPh3)2(3-phenylindenyl)] (1) has been shown to be an efficient catalyst in thiol dehydrogenative coupling to give disulfides. Moreover, an efficient procedure for the preparation of silylthioethers and thioboranes is presented. Complex 1 demonstrated a great ability to catalyse the coupling of thiols with silanes and boranes under mild conditions with excellent results (turnover number up to 200).