1444922-78-4

Basic information

• Product Name: C₃₀H₂₃AuN₄O₂P⁽¹⁺⁾*CF₃O₃S^(1-)
• CAS NO: 1444922-78-4
• Molecular Weight: 848.549
• Mol File: 1444922-78-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₀H₂₃AuN₄O₂P⁽¹⁺⁾*CF₃O₃S^(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₀H₂₃AuN₄O₂P⁽¹⁺⁾*CF₃O₃S^(1-)(1444922-78-4)
• EPA Substance Registry System: C₃₀H₂₃AuN₄O₂P⁽¹⁺⁾*CF₃O₃S^(1-)(1444922-78-4)

Safety Data

• Hazardous Substances Data: 1444922-78-4(Hazardous Substances Data)

Upstream product

• 14243-64-2 (triphenylphosphine)gold(I) chloride 
• 4490-51-1 1-(4-nitrophenyl)-1H-benzo[d][1,2,3]triazole 
• 2923-28-6 silver trifluoromethanesulfonate 

Relevant articles and documents

Quantitative kinetic investigation of triazole-gold(i) complex catalyzed [3,3]-rearrangement of propargyl ester

The triazole-gold(i) complex catalyzed [3,3]-rearrangement of propargyl ester has been quantitatively investigated through in situ IR. First order dependence of the initial rates on [Au] and [propargyl ester] suggested that the turnover-limiting step is the associative ligand substitution. The activation enthalpy was also determined to be 7.8 kcal mol-1. TA-Au catalysts with different triazole derivatives were also tested, giving a linear free energy relationship with a ρ value of 0.74. The Royal Society of Chemistry.