14453-85-1

Basic information

• Product Name: Benzenamine, 4-[(4-methoxyphenyl)thio]-
• CAS NO: 14453-85-1
• Molecular Formula: C13H13NOS
• Molecular Weight: 231.318
• Mol File: 14453-85-1.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-[(4-methoxyphenyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-[(4-methoxyphenyl)thio]-(14453-85-1)
• EPA Substance Registry System: Benzenamine, 4-[(4-methoxyphenyl)thio]-(14453-85-1)

Safety Data

• Hazardous Substances Data: 14453-85-1(Hazardous Substances Data)

Upstream product

• 1193-02-8 4-aminotiophenol 
• 722-27-0 bis(4-aminophenyl)disulfide 
• 696-62-8 para-iodoanisole 
• 540-37-4 p-aminoiodobenzene 
• 696-63-9 4-Methoxybenzenethiol 
• 62-53-3 aniline 
• 350-46-9 4-Fluoronitrobenzene 
• 100-00-5 4-chlorobenzonitrile 
• 22865-50-5 4-(4-methoxyphenylsulfanyl)nitrobenzene 
• 104-92-7 1-bromo-4-methoxy-benzene 

Downstream Products

• 37930-94-2 4-(4-Methoxiphenylthio)-trifluormethansulfonanilid 
• 38007-64-6 4-Bromacetylamino-4'-methoxydiphenylsulfid 
• 53279-53-1 4-(4-methoxyphenylthio)benzylamine 
• 53279-55-3 4-(4-Aminomethyl-phenylsulfanyl)-phenol 
• 53279-54-2 4-(4-hydroxyphenylthio)benzonitrile 
• 37924-33-7 4-(4-Methoxiphenylsulfonyl)-trifluormethansulfonanilid 
• 37924-32-6 4-(4-Methoxiphenylsulfinyl)-trifluormethansulfonanilid 
• 861083-81-0 (4-iodophenyl)(4-methoxyphenyl)thioether 

Relevant articles and documents

Dimsyl Anion Enables Visible-Light-Promoted Charge Transfer in Cross-Coupling Reactions of Aryl Halides

A methodology is reported for visible-light-promoted synthesis of unsymmetrical chalcogenides enabled by dimsyl anion in the absence of transition-metals or photoredox catalysts. The cross-coupling reaction between aryl halides and diaryl dichalcogenides proceeds with electron-rich, electron-poor, and heteroaromatic moieties. Mechanistic investigations using UV-Vis spectroscopy, time-dependent density functional theory (TD-DFT) calculations, and control reactions suggest that dimsyl anion forms an electron-donor-acceptor (EDA) complex capable of absorbing blue light, leading to a charge transfer responsible for generation of aryl radicals from aryl halides. This previously unreported mechanistic pathway may be applied to other light-induced transformations performed in DMSO in the presence of bases and aryl halides.

Flavin/I2 catalyzed aerobic oxidative C–H sulfenylation of anilines

A flavin/I2 catalyzed aerobic oxidative C–H sulfenylation of anilines with thiols under mild reaction conditions is presented for the first time. This metal-free reaction provides an atom-economic pathway to prepare various aryl sulfides with outstanding functional group compatibility. Moreover, it consumes molecular oxygen as the only terminal oxidant and produces environmentally-friendly H2O as the only byproduct.

HETEROCYCLIC CARBOXYLIC ACID AMIDE LIGAND AND APPLICATIONS THEREOF IN COPPER CATALYZED COUPLING REACTION OF ARYL HALOGENO SUBSTITUTE

Provided are a heterocyclic carboxylic acid amide ligand and applications thereof in a copper catalyzed coupling reaction. Specifically, provided are uses of a compound represented by formula (I), definitions of radical groups being described in the specifications. The compound represented by formula (I) can be used as the ligand in the copper catalyzed coupling reaction of the aryl halogeno substitute, and is used or catalyzing the coupling reaction for forming the aryl halogeno substitute having C—N, C—O, C—S and other bonds.