144613-92-3

Basic information

• Product Name: [PtCl₂(P(OC₆H₄OCH₃)3)2]
• CAS NO: 144613-92-3
• Molecular Weight: 1066.72
• Mol File: 144613-92-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [PtCl₂(P(OC₆H₄OCH₃)3)2](CAS DataBase Reference)
• NIST Chemistry Reference: [PtCl₂(P(OC₆H₄OCH₃)3)2](144613-92-3)
• EPA Substance Registry System: [PtCl₂(P(OC₆H₄OCH₃)3)2](144613-92-3)

Safety Data

• Hazardous Substances Data: 144613-92-3(Hazardous Substances Data)

Upstream product

• 12080-32-9 dichloro(1,5-cyclooctadiene)platinum(ll) 
• 36370-75-9 tris(2-methoxyphenyl) phosphite 

Downstream Products

• 176510-17-1 [PtH(CN)(P(OC₆H₄OCH₃)3)2] 
• 144613-81-0 Pt(C₂Cl₂H₂){P(OC₆H₄OCH₃)3}2 
• 144613-82-1 Pt{P(OC₆H₄OCH₃)3}2(H₂CCHCN) 
• 144613-83-2 Pt{P(OC₆H₄OCH₃)3}2(H₂CCHCHO) 
• 144613-84-3 Pt{P(OC₆H₄OCH₃)3}2(HCCC₆H₅) 
• 144613-80-9 Pt{P(OC₆H₄OCH₃)3}2(H₂CCHC₆H₅) 
• 144613-79-6 Pt{P(OC₆H₄OCH₃)3}2(C₇H₁₀) 
• 176510-19-3 [Pt(C₂H₅)2(P(OC₆H₄OCH₃)3)2] 
• 144613-77-4 [Pt(P(OC₆H₄OCH₃)3)3] 
• 144613-78-5 [Pt(C₂H₄)(P(OC₆H₄OCH₃)3)2] 

Relevant articles and documents

Tris(2-methoxyphenyl) phosphite complexes of platinum(n): The cis preference of triaryl phosphite ligands and the effect of oxidation state on metal-phosphite bonding

The complexes cis-[PtX2{P(OC6H4OMe-2)3} 2] (X = Cl, Br or I) have been prepared by treatment of the corresponding [PtX2(cod)] (cod = cycloocta-1,5-diene) with P(OC6H4OMe-2)3. That with X = Cl reacted with 1 or 2 equivalents of SnCl2 to give cis-[PtCl(SnCl3){P(OC6H4OMe-2) 3}2] or trans-[Pt(SnCl3)2{P(OC6H4OMe-2) 3}2]. The unstable hydride trans-[PtH(Cl){P(OC6H4OMe-2)3}2] was detected when cis-[PtCl2{P(OC6H4OMe-2)3} 2] was treated with NaBH4 or [Pt{P(OC6H4OMe-2)3}3] with HCl. The organoplatinum complexes cis-[PtR2{P(OC6H4OMe-2)3} 2] and cis-[PtR(X){P(OC6H4OMe-2)3}2] (R = Me, X = Cl, I or CN; R = Et, X = Cl) were obtained from platinum-(II) and -(0) precursors. Addition of HBF4 to cis-[PtMe2{P(OC6H4OMe-2)3} 2], in the presence of H2O or MeCN, gave the cationic species cis-[PtMe(L){P(OC6H4OMe-2)3} 2][BF4] (L = H2O or MeCN). The significance of the observation that complexes of the type [PtMe(L){P(OC6H4OMe-2)3}2] are invariably cis is discussed. The crystal structures of cis-[PtCl2{P(OC6H4OMe-2)3} 2] and cis-[PtMe(OH2){P(OC6H4OMe-2)3} 2][BF4]·CH2Cl2 have been determined. These, together with those previously reported for P(OC6H4OMe-2)3 and [Pt(η-C2H4)-{P(OC6H4OMe-2) 3}2], show pronounced variation in P-O lengths and O-P-O bond angles consistent with the greater importance of Pt-P π bonding in the platinum(0) species. The phosphite P(OC6H4OMe-2)3 shows a range of conformations in the structures and that with anti, gauche, gauche (agg) conformation about the P-O bonds apparently favoured in general but ggg attainable in the absence of steric crowding. In cis-[PtMe(OH2){P(OC6H4OMe-2)3} 2][BF4]·CH2Cl2, intramolecular hydrogen bonding leads to an unusual aag conformation. Weak Pt ... O interactions involving the OMe groups of the phosphite ligand are observed in these structures. The correlation of P-O length and O-P-O angle variation is mirrored by similar behaviour for 133 Z-P(OPh)3 (Z = O, N or metal) structures. These observations are consistent with the now conventional view of M-P π bonding.