1446203-82-2Relevant articles and documents
1,5,7-triazabicyclo[4.4.0]dec-1-ene-mediated acetylene dicarboxylation and alkyne carboxylation using carbon dioxide
Wang, Xi,Lim, Yu Na,Lee, Chan,Jang, Hye-Young,Lee, Bun Yeoul
, p. 1867 - 1871 (2013)
Direct carboxylation of acetylene with CO2 was carried out in the presence of 1,5,7-triazabicyclo[4.4.0]dec-1-ene (TBD); subsequent reduction of dicarboxylated acetylene produces commercially valuable succinate salts. This metal-free carboxylation has potential economic and environmental impact by utilizing non-petroleum feedstocks (acetylene) and CO2 and by producing valuable chemical feed stocks. Direct carboxylation of acetylene with CO2 was carried out in the presence of 1,5,7-triazabicyclo[4.4.0]dec- 1-ene (TBD); subsequent reduction of dicarboxylated acetylene produces commercially valuable succinate salts. This metal-free carboxylation has potential economic and environmental impact by utilizing non-petroleum feedstocks (acetylene) and CO2 and by producing valuable chemical feed stocks.