1446412-05-0

Basic information

• Product Name: [2-(dimethylaminomethyl)phenyl]diphenyllead(IV)diethyldithiocarbamate
• CAS NO: 1446412-05-0
• Molecular Weight: 643.885
• Mol File: 1446412-05-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [2-(dimethylaminomethyl)phenyl]diphenyllead(IV)diethyldithiocarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: [2-(dimethylaminomethyl)phenyl]diphenyllead(IV)diethyldithiocarbamate(1446412-05-0)
• EPA Substance Registry System: [2-(dimethylaminomethyl)phenyl]diphenyllead(IV)diethyldithiocarbamate(1446412-05-0)

Safety Data

• Hazardous Substances Data: 1446412-05-0(Hazardous Substances Data)

Upstream product

• 20624-25-3 sodium diethyldithiocarbamate trihydrate 

Relevant articles and documents

Hypervalent triorganolead(iv) dithiocarbamates containing a 2-(me2nch2)c6h4 group. crystal and molecular structure of [2-(Me2NCH2)C6H4]Ph2PbS(S)CNR2 (R = Me, Et)

Two new triorganolead(IV) dithiocarbamates, [2-(Me2NCH2)C6H4]Ph2PbS(S)CNR2 [R = Me (1), Et (2)] were prepared by reacting [2-(Me2NCH2)C6H4]Ph2PbI with the corresponding sodium dithio ligand. Both compounds were characterized by multinuclear NMR solution studies and their crystal and molecular structure was established by single-crystal X-ray diffraction. In both cases the nitrogen atom from the pendant Me2NCH2 arm is coordinated intramolecularly to the metal centre [Pb(1)-N(1) 2.788(5) A in 1 and 2.764(11) A in 2, respectively] in trans to a sulfur atom [S(1)-Pb(1)-N(1) 168.89(10) in 1 and 170.3(2) in 2, respectively]. This results in a distorted trigonal bipyramidal geometry around the lead atom of hypervalent 10-Pb-5 species. Compounds 1 and 2 crystallize as 1:1 mixtures of RN1- and SN1-isomers (planar chirality induced by the non-planar PbC3N chelate ring). In the crystals weak intermolecular S··H and C-H··π (Phcentroid) contacts result in different supramolecular architectures.