144758-83-8Relevant articles and documents
Preparation method of cyanalcohol silyl ether compound
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Paragraph 0074; 0075; 0076, (2019/01/06)
The invention discloses a preparation method of a cyanalcohol silyl ether compound. The preparation method comprises usage of a catalyst, the catalyst is a tridentate forceps-shaped ligand-stabilizedmagnesium lithium bimetallic compound. According to the
Efficient and selective aldehyde cyanosilylation catalyzed by Mg-Li bimetallic complex
Li, Jia,Yu, Ting,Luo, Man,Xiao, Qian,Yao, Weiwei,Xu, Li,Ma, Mengtao
, p. 83 - 86 (2018/09/06)
A NCN-pincer ligand-based Mg-Li bimetallic complex [NCN-MgBr2][Li(THF)4] 1 has been employed as an efficient catalyst for cyanosilylation of a wide range of aldehydes with trimethylsilyl cyanide (TMSCN) at room temperature in CDClsu
Stereoselective construction of cis-decalin framework via radical domino cyclization
Suzuki, Eriko,Ueda, Minoru,Ohba, Shigeru,Sugai, Takeshi,Shoji, Mitsuru
, p. 1589 - 1592 (2013/03/28)
Steroids with A/B cis-decalin moiety and various bioactivities have attracted many synthetic chemists as target molecules and development of efficient methodology providing cis-decalins has been desired. A stereoselective domino cyclization via Mn(OAc)3 and Cu(OTf)2-mediated radical reaction was found to be effective to construct cis-decalin framework.