144776-76-1Relevant articles and documents
Rhodium-catalyzed transformation of propargyl alcohol derivatives to 2-silylmethyl-2-alkenals
Matsuda, Isamu,Niikawa, Nakayoshi,Kuwabara, Rika,Inoue, Hirofumi,Nagashima, Hideo,Itoh, Kenji
, p. 133 - 141 (2007/10/03)
Propargyl-type alcohols (6) and the corresponding esters of carbonic acid (4) or acetic acid (5) react with two equivalents of Me2PhSiH in the presence of catalytic amounts of Rh4(CO)12 under CO pressure at 100°C to give 2