1448243-39-7

Basic information

• Product Name: (3S,4R,5R)-5-(prop-1-en-2-yl)-3,4-bis((triisopropylsilyl)oxy)dihydrofuran-2(3H)-one
• Synonyms: (3S,4R,5R)-5-(prop-1-en-2-yl)-3,4-bis((triisopropylsilyl)oxy)dihydrofuran-2(3H)-one
• CAS NO: 1448243-39-7
• Molecular Weight: 470.841
• Mol File: 1448243-39-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3S,4R,5R)-5-(prop-1-en-2-yl)-3,4-bis((triisopropylsilyl)oxy)dihydrofuran-2(3H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4R,5R)-5-(prop-1-en-2-yl)-3,4-bis((triisopropylsilyl)oxy)dihydrofuran-2(3H)-one(1448243-39-7)
• EPA Substance Registry System: (3S,4R,5R)-5-(prop-1-en-2-yl)-3,4-bis((triisopropylsilyl)oxy)dihydrofuran-2(3H)-one(1448243-39-7)

Safety Data

• Hazardous Substances Data: 1448243-39-7(Hazardous Substances Data)

Upstream product

• 1448243-38-6 (3S,4S,5R)-3,4-dihydroxy-5-(prop-1-en-2-yl)dihydrofuran-2(3H)-one 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 

Relevant articles and documents

A C2-symmetric pool based synthesis of the furanoside of hygromycin A

The readily available and inexpensive D-tartaric acid serves as the chiral building block for synthesis of the furanoside of hygromycin A. Key to our successes in the asymmetric synthesis of the furanose segment was the melding of several key reactions, such as the successful application of the monosilylation of C2-symmetric diol, diastereocontrolled di(2-propenyl)zinc addition to the aldehyde, and TMSCl-MeOH promoted desilylation, acetal-cleavage, and intramolecular esterification in one-step.