1448461-04-8Relevant articles and documents
Syntheses of the hexahydroindene cores of indanomycin and stawamycin by combinations of iridium-catalyzed asymmetric allylic alkylations and intramolecular diels-alder reactions
G?rtner, Martin,Satyanarayana, Gedu,F?rster, Sebastian,Helmchen, Günter
supporting information, p. 400 - 405 (2013/02/25)
Short and concise syntheses of the hexahydroindene cores of the antibiotics indanomycin (X-14547 A) and stawamycin are presented. Key methods used are an asymmetric iridium-catalyzed allylic alkylation, a modified Julia olefination, a Suzuki-Miyaura coupling, and an intramolecular Diels-Alder reaction.