1448582-17-9

Basic information

• Product Name: (-)-(2S)-benzyl 2-(3-ethylbenzyl)-2,3-dimethyl-4-oxoimidazolidine-1-carboxylate
• CAS NO: 1448582-17-9
• Molecular Weight: 366.46
• Mol File: 1448582-17-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (-)-(2S)-benzyl 2-(3-ethylbenzyl)-2,3-dimethyl-4-oxoimidazolidine-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(2S)-benzyl 2-(3-ethylbenzyl)-2,3-dimethyl-4-oxoimidazolidine-1-carboxylate(1448582-17-9)
• EPA Substance Registry System: (-)-(2S)-benzyl 2-(3-ethylbenzyl)-2,3-dimethyl-4-oxoimidazolidine-1-carboxylate(1448582-17-9)

Safety Data

• Hazardous Substances Data: 1448582-17-9(Hazardous Substances Data)

Upstream product

• 91166-27-7 1-(3-ethylphenyl)propan-2-one 
• 22699-70-3 3-ethylacetophenone 
• 1448582-14-6 2-(3-ethylbenzyl)-2,3-dimethylimidazolidin-4-one 

Downstream Products

• 1448582-18-0 (+)-(2R)-2-(3-ethylbenzyl)-2,3-dimethylimidazolidin-4-one 

Relevant articles and documents

Enantioselective direct α-amination of aldehydes via a photoredox mechanism: A strategy for asymmetric amine fragment coupling

The direct, asymmetric α-amination of aldehydes has been accomplished via a combination of photoredox and organocatalysis. Photon-generated N-centered radicals undergo enantioselective α-addition to catalytically formed chiral enamines to directly produce stable α-amino aldehyde adducts bearing synthetically useful amine substitution patterns. Incorporation of a photolabile group on the amine precursor obviates the need to employ a photoredox catalyst in this transformation. Importantly, this photoinduced transformation allows direct and enantioselective access to α-amino aldehyde products that do not require postreaction manipulation.