144877-34-9Relevant articles and documents
The First Monomeric Prochiral Tin(II) Complexes SnX t2-2,6-Me-4, 1 or , 2>; the X-Ray Structure of 1 and Oxidative Addition Reactions of 2
Braunschweig, Holger,Chorley, Richard W.,Hitchcock, Peter B.,Lappert, Michael F.
, p. 1311 - 1313 (2007/10/02)
Monomeric, crystalline tin(II) amides Sn(NR2)X t2-2,6-Me-4, NR'2 = > have been prepared from (a) Sn(NR2)2 + SnX2, (b) 2 + 2LiX or (c) Sn(NR2)2 + ArOH; 1 is V-shaped, O-Sn-N 96.4(1) deg; 2 + A-B yields the adducts Sn(A)(B)(NR2)(NR'2) , in the case of 5 without significant diastereoselectivity.