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1449590-11-7

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1449590-11-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1449590-11-7 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,4,4,9,5,9 and 0 respectively; the second part has 2 digits, 1 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 1449590-11:
(9*1)+(8*4)+(7*4)+(6*9)+(5*5)+(4*9)+(3*0)+(2*1)+(1*1)=187
187 % 10 = 7
So 1449590-11-7 is a valid CAS Registry Number.

1449590-11-7Downstream Products

1449590-11-7Relevant articles and documents

Employing Water as the Hydride Source in Synthesis: A Case Study of Diboron Mediated Alkyne Hydroarylation

Rao, Santhosh,Joy, M. Nibin,Prabhu, Kandikere Ramaiah

, p. 13707 - 13715 (2018/11/30)

We present an approach to utilize water as the hydride source via Pd(II)/Pd(0) catalysis. As a case study, we have achieved a diboron mediated Pd(II)-catalyzed hydroarylation of alkynes using arylboronic acids. This approach not only complements conventional reactivity of Pd via Pd(0)/Pd(II) cycle for the hydroarylation but also utilizes water as the hydride source. We believe this would particularly be beneficial in utilizing water as a reagent.

Palladium-catalyzed desulfitative hydroarylation of alkynes with sodium sulfinates

Liu, Saiwen,Bai, Yang,Cao, Xiangxiang,Xiao, Fuhong,Deng, Guo-Jun

supporting information, p. 7501 - 7503 (2013/08/23)

A palladium-catalyzed desulfitative hydroarylation of alkynes with aryl sulfinic acid sodium salts is described. The reaction showed good regio- and stereoselectivity, and afforded the hydroarylation products in good yields. Various functional groups were well tolerated under the optimized reaction conditions.

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