1454372-39-4Relevant articles and documents
Base-free production of H2 by dehydrogenation of formic acid using an iridium-bisMETAMORPhos complex
Oldenhof, Sander,De Bruin, Bas,Lutz, Martin,Siegler, Maxime A.,Patureau, Frederic W.,Van Der Vlugt, Jarl Ivar,Reek, Joost N. H.
, p. 11507 - 11511 (2013)
Erase the base: An iridium complex based on a cooperative ligand that functions as an internal base is reported. This complex can rapidly and cleanly dehydrogenate formic acid in absence of external base, a reaction that is required if formic acid is to be exploited as an energy carrier (see scheme). Copyright