1454704-55-2Relevant articles and documents
Regioselective C2 oxidative olefination of indoles and pyrroles through cationic rhodium(III)-Catalyzed C-H bond activation
Li, Bin,Ma, Jianfeng,Xie, Weijia,Song, Haibin,Xu, Shansheng,Wang, Baiquan
supporting information, p. 11863 - 11868 (2013/09/23)
Be economic with your atoms! An efficient Rh-catalyzed oxidative olefination of indoles and pyrroles with broad substrate scope and tolerance is reported (see scheme). The catalytic reaction proceeds with excellent regio- and stereoselectivity. The directing group N,N-dimethylcarbamoyl was crucial for the reaction and could be removed easily. Copyright
Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group
Zhang, Luo-Qiang,Yang, Shiping,Huang, Xiaolei,You, Jingsong,Song, Feijie
supporting information, p. 8830 - 8832 (2013/09/24)
A highly efficient and selective Ru-catalyzed direct C2-olefination of indoles, pyrroles, and carbazoles assisted by a removable N-dimethylcarbamoyl group has been developed by using O2 as the terminal oxidant. Both electron-deficient and unactivated alkenes are applicable to the protocol. The Royal Society of Chemistry 2013.