14548-01-7

Basic information

• Product Name: PHENANTHRIDINE5-OXIDE
• Synonyms: PHENANTHRIDINE5-OXIDE
• CAS NO: 14548-01-7
• Molecular Formula: C₁₃H₉NO
• Molecular Weight: 195.21666
• Mol File: 14548-01-7.mol
• Article Data: 17

Chemical Properties

• Boiling Point: 408.9°Cat760mmHg
• Flash Point: 201.1°C
• Appearance: /
• Density: 1.18g/cm³
• Vapor Pressure: 1.6E-06mmHg at 25°C
• Refractive Index: 1.645
• CAS DataBase Reference: PHENANTHRIDINE5-OXIDE(CAS DataBase Reference)
• NIST Chemistry Reference: PHENANTHRIDINE5-OXIDE(14548-01-7)
• EPA Substance Registry System: PHENANTHRIDINE5-OXIDE(14548-01-7)

Safety Data

• Hazardous Substances Data: 14548-01-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H9NO/c15-14-9-10-5-1-2-6-11(10)12-7-3-4-8-13(12)14/h1-9H

Upstream product

• 79-21-0 peracetic acid 
• 229-87-8 phenanthridine 
• 2311-91-3 monoperoxyphthalic acid 
• 894-82-6 (2'-nitro-biphenyl-2-yl)-acetic acid methyl ester 
• 100725-86-8 (2'-nitro-biphenyl-2-yl)-acetic acid 
• 100872-53-5 (2'-nitro-biphenyl-2-yl)-acetic acid amide 

Downstream Products

• 229-87-8 phenanthridine 
• 2720-93-6 6-phenylphenanthridine 
• 75121-06-1 (Z)-2-(phenanthridin-6-yl)-1-phenylethen-1-ol 
• 16573-58-3 6-cyclohexylphenanthridine N-oxide 
• 3955-65-5 6-methylphenanthridine 
• 3900-22-9 6-methylphenanthridine 5-oxide 
• 27799-79-7 5,6-dihydrophenanthridine 
• 16573-51-6 6-benzyl-phenanthridine 
• 1620101-17-8 4-(4-methylphenylsulfonamido)phenanthridine 5-oxide 
• 77464-48-3 2,2-diphenyl-3,4-benzoquinoline-1-oxyl 
• 37045-19-5 5-ethoxycarbonylmethyl-6-phenanthridone 

Relevant articles and documents

Synthesis of heteroaromatic trifluoromethyl ethers with trifluoromethyl triflate as the source of the trifluoromethoxy group

A series of nitrogen-heterocycles have been transformed to the corresponding trifluoromethyl or higher perfluoroalkyl ethers by reaction of the corresponding N-oxides with trifluoromethyl or higher perfluoroalkyl triflate. Trifluoromethyl triflate, which has generally been used as a precursor to [OCF3]?, is used here as a bifunctional reagent to render the heteroarene more electrophilic and to deliver the trifluoromethoxy group. This reagent was easily prepared on a large scale (>100 grams) and is stable in either pure form or as a stock solution. Applications and limitations of this method are reported.

2-Position-selective C[sbnd]H fluoromethylation of six-membered heteroaryl N-oxides with (fluoromethyl)triphenylphosphonium iodide

A mild and efficient method for the regioselective C[sbnd]H fluoromethylation of heteroaryl N-oxides with (fluoromethyl)triphenylphosphonium iodide is presented. With LiOt-Bu as the base and DMSO as the solvent, this reaction delivers a series of C2-fluor

Co(III)-Catalyzed C-H Amidation of Nitrogen-Containing Heterocycles with Dioxazolones under Mild Conditions

A cobalt(III)-catalyzed C-8 selective C-H amidation of quinoline N-oxide using dioxazolone as an amidating reagent under mild conditions is disclosed. The reaction proceeds efficiently with excellent functional group compatibility. The utility of the current method is demonstrated by gram scale synthesis of C-8 amide quinoline N-oxide and by converting this amidated product into functionalized quinolines. Furthermore, the developed catalytic method is also applicable for C-7 amidation of N-pyrimidylindolines and ortho-amidation of benzamides.