145527-19-1Relevant articles and documents
Thermal rearrangement of thiocarbonyl-stabilised triphenylphosphonium ylides leading to (Z)-1-diphenylphosphino-2-phenylsulfenylalkenes
Alan Aitken,Dawson, Graham,Keddie, Neil S.,Kraus, Helmut,Slawin, Alexandra M. Z.,Wheatley, Joanne,Woollins, J. Derek
body text, p. 7381 - 7383 (2010/06/13)
While thermolysis of thiocarbonyl-stabilised phosphonium ylides generally results in extrusion of Ph3PS to give alkynes, those with a PCH function instead undergo a novel P to S transfer of a phenyl group to give (Z)-configured 1-phosphino-2-su