145788-28-9Relevant articles and documents
A Novel Synthesis Including Asymmetric Synthesis of α,β-Unsaturated γ-Hydroxy Carbonyl Compounds from Enones with Carbon Homologation
Satoh, Tsuyoshi,Motohashi, Shigeyasu,Tokutake, Norio,Yamakawa, Koji
, p. 2966 - 2973 (2007/10/02)
Reaction of the carbanion derived from 1-chloroalkyl aryl sulfoxides with enones gave 1,2-adducts in good yields.Treatment of the adduct with potassium benzenethiolate afforded α-phenylthio β,γ-unsaturated carbonyl compound through an α,β-epoxy sulfoxide.