145852-78-4

Basic information

• Product Name: 1-Benzyloxymethyl-3-bromo-4-(7-chloro-1H-indol-3-yl)-pyrrole-2,5-dione
• CAS NO: 145852-78-4
• Molecular Weight: 445.7
• Mol File: 145852-78-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-Benzyloxymethyl-3-bromo-4-(7-chloro-1H-indol-3-yl)-pyrrole-2,5-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Benzyloxymethyl-3-bromo-4-(7-chloro-1H-indol-3-yl)-pyrrole-2,5-dione(145852-78-4)
• EPA Substance Registry System: 1-Benzyloxymethyl-3-bromo-4-(7-chloro-1H-indol-3-yl)-pyrrole-2,5-dione(145852-78-4)

Safety Data

• Hazardous Substances Data: 145852-78-4(Hazardous Substances Data)

Upstream product

• 3587-60-8 Benzyloxymethyl chloride 
• 53924-05-3 7-chloro-1H-indole 
• 102147-52-4 N-benzyloxymethyl-3,4-dibromomaleimide 

Downstream Products

• 145852-81-9 3,4-dihydro-3-<7-chloro-1-<<2-(trimethylsilyl)ethoxy>methyl>-1H-indol-3-yl>-4-(7-chloro-1-(3,6-di-O-benzyl-4-O-methyl-β-D-glucopyranosyl)-1H-indol-3-yl)-1-(benzyloxymethyl)-1H-pyrrole-2,5-dione 
• 145852-83-1 3,4-dihydro-3-<7-chloro-1H-indol-3-yl>-4-(7-chloro-1-(3,6-di-O-benzyl-4-O-methyl-β-D-glucopyranosyl)-1H-indol-3-yl)-1-(benzyloxymethyl)-1H-pyrrole-2,5-dione 
• 145852-80-8 3,4-dihydro-3-<7-chloro-1-<<2-(trimethylsilyl)ethoxy>methyl>-1H-indol-3-yl>-4-(7-chloro-1H-indol-3-yl)-1-(benzyloxymethyl)-1H-pyrrole-2,5-dione 
• 145852-79-5 4-bromo-3,4-dihydro-3-<7-chloro-1-<<2-(trimethylsilyl)ethoxy>methyl>-1H-indol-3-yl>-1-(benzyloxymethyl)-1H-pyrrole-2,5-dione 

Relevant articles and documents

A Stereoselective Synthesis of Indole-β-N-glycosides: An Application to the Synthesis of Rebeccamycin

Sodium salts of indoles have been found to open α-1,2-anhydrosugars with inversion yielding indole-β-N-glycosides.This methodology constitutes a concise route from glycals to the biologically active indole-N-glycosides.An application to the total synthesis of rebeccamycin is descibed.