14586-54-0 Usage
Description
1,10-Phenanthroline Iron(II) Perchlorate is a chemical compound that serves as an oxidation-reduction indicator. It is characterized by its ability to change color in response to changes in oxidation or reduction conditions, making it a valuable tool in various analytical and research applications.
Uses
1. Used in Chemical Analysis:
1,10-Phenanthroline Iron(II) Perchlorate is used as an oxidation-reduction indicator for the detection, identification, and analysis of chemical processes or conditions. Its color change properties allow for the monitoring of reactions and the determination of reaction endpoints.
2. Used in Biological and Pathologic Studies:
1,10-PHENANTHROLINE IRON(II) PERCHLORATE is also utilized in the study of biological and pathologic processes or conditions. Its ability to act as an oxidation-reduction indicator can help researchers understand the behavior of certain biological systems and identify potential therapeutic targets.
3. Used in DNA Research:
1,10-Phenanthroline Iron(II) Perchlorate is employed as an agent that can interact with DNA, causing it to kink, uncoil, or deform. This interaction prevents the proper functioning of DNA, which is crucial for its role in various cellular processes. This property makes it a valuable tool in the study of DNA structure and function, as well as in the development of potential DNA-targeting therapeutics.
Check Digit Verification of cas no
The CAS Registry Mumber 14586-54-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,5,8 and 6 respectively; the second part has 2 digits, 5 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 14586-54:
(7*1)+(6*4)+(5*5)+(4*8)+(3*6)+(2*5)+(1*4)=120
120 % 10 = 0
So 14586-54-0 is a valid CAS Registry Number.
InChI:InChI=1/C5H8O2.Li/c1-4(6)3-5(2)7;/h3,6H,1-2H3;/q;+1/p-1/b4-3-;/rC5H7LiO2/c1-4-3-5(2)8-6-7-4/h3H,1-2H3
14586-54-0Relevant articles and documents
Effect of Nucleophiles on the Rates of Dissociation and Racemization of the Tris(1,10-phenanthroline)iron(II) Ion in Aqueous Solutions
Tachiyashiki, Satoshi,Yamatera, Hideo
, p. 1014 - 1021 (1982)
The rates of dissociation and racemization of the tris(1,10-phenanthroline)iron(II) ion were obtained in aqueous solutions containing fourteen ikinds of nucleophile.They ranged from 0.7 to 9.3 and from 0.9 to 3.2 times the rates in pure water, respectively.The results were analyzed by considering simultaneous reactions of free and ion-paired complex ions.The rate constants of the dissociation (ligand release) of the complex existing in ion-pairs increased in the following order of the counter-ions: I--------- ca.CN-; here H2O is regarded as a nucleophile for the free complex ion.This order is similar to that of proton affinities of nucleophiles.The results show that the dissociation is accelerated by ? donation from the nucleophile, suggesting an ion-pair interchange mechanism.The inramolecular racemization rate constant, given by total recemization rate constant minus dissociation rate constant, increased in the following order of nucleophiles: OH- ca.CN- ca.F- ca.Cl- - ca.NO2- - - - - - ca.SeCN- a greater effect than their basicity.The operation of ? interaction between the complex ion and the nucleophile in the transition state is also suggested.The ion-association constants obtained from the rate data were in the range of 1 to 8 (I=1.0, 32.0 deg C).
