145901-77-5

Basic information

• Product Name: 2,3-dimethyl-6-methoxybenzaldehyde
• Synonyms: 2,3-dimethyl-6-methoxybenzaldehyde
• CAS NO: 145901-77-5
• Molecular Weight: 164.204
• Mol File: 145901-77-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,3-dimethyl-6-methoxybenzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-dimethyl-6-methoxybenzaldehyde(145901-77-5)
• EPA Substance Registry System: 2,3-dimethyl-6-methoxybenzaldehyde(145901-77-5)

Safety Data

• Hazardous Substances Data: 145901-77-5(Hazardous Substances Data)

Upstream product

• 4685-47-6 3,4-dimethylanisole 
• 68-12-2 N,N-dimethyl-formamide 
• 67-56-1 methanol 
• 5779-93-1 2,3-dimethylbenzaldehyde 

Relevant articles and documents

Monodentate Transient Directing Group Enabled Pd-Catalyzed Ortho-C-H Methoxylation and Chlorination of Benzaldehydes

We report Pd-catalyzed ortho-C-H methoxylation and chlorination of benzaldehydes by employing monodentate transient directing groups (TDGs) as an alternative strategy to bidentate TDGs. More importantly, a single crystal of benzaldehyde imine ortho-cyclopalladium intermediate was successfully obtained, and its structure was unambiguously determined by X-ray diffraction, which clearly showed that it was a binuclear palladium species bridged by a pyridone ligand. The utility of this approach was further demonstrated through the synthesis of key intermediates of natural products and drugs.