1459129-50-0Relevant articles and documents
Unexpected synthesis of novel O -ethyl- P -aryl- N -(thiophen-2-yl) phosphonamidothioates from ethyl 2-aminothiophene- 3-carboxylates and Lawesson's reagent
Khalladi, Khaoula,Touil, Soufiane
, p. 145 - 151 (2014/01/23)
The reaction of ethyl 2-aminothiophene-3-carboxylates with a stoichiometric amount of Lawesson's reagent (LR) gave novel O-ethyl-P-aryl-N-(thiophen-2-yl) phosphonamidothioate derivatives rather than the expected thienothiazaphosphorines. A possible reaction mechanism, involving a carbonyl sulfide extrusion, is proposed.