146029-61-0

Basic information

• Product Name: Methyl (2S,4S)-2-(indol-3-ylmethyl)-4-(2,4-dinitroanilino)-5-oxo-2,3,4,5-tetrahydrofuran-2-carboxylate
• CAS NO: 146029-61-0
• Molecular Weight: 454.396
• Mol File: 146029-61-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methyl (2S,4S)-2-(indol-3-ylmethyl)-4-(2,4-dinitroanilino)-5-oxo-2,3,4,5-tetrahydrofuran-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl (2S,4S)-2-(indol-3-ylmethyl)-4-(2,4-dinitroanilino)-5-oxo-2,3,4,5-tetrahydrofuran-2-carboxylate(146029-61-0)
• EPA Substance Registry System: Methyl (2S,4S)-2-(indol-3-ylmethyl)-4-(2,4-dinitroanilino)-5-oxo-2,3,4,5-tetrahydrofuran-2-carboxylate(146029-61-0)

Safety Data

• Hazardous Substances Data: 146029-61-0(Hazardous Substances Data)

Upstream product

• 146142-94-1 (2S,4S)-2-((1H-indol-3-yl)methyl)-4-amino-2-hydroxypentane-1,5-dioic acid 
• 70-34-8 2,4-Dinitrofluorobenzene 
• 186581-53-3 diazomethane 

Relevant articles and documents

Structure Elucidation of Monatin, a High-intensity Sweetener Isolated from the Plant Schlerochiton ilicifolius

The structure of monatin, a high-intensity sweetener isolated from Schlerochiton ilicifolius was elucidated by 1H and 13C NMR spectroscopy as 4-hydroxy-4-(indol-3-ylmethyl)glutamic acid.The 2R*,4R* relative configuration of the two chiral centres in monatin was determined by NOE studies on a derivative, methyl 2-(indol-3-ylmethyl)-4-(2,4-dinitroanilino)-5-oxo-2,3,4,5-tetrahydrofuran-2-carboxylate.The assignment of the 2S configuration to monatin, through application of the Clough-Lutz-Jirgenson rule, established the 2S,4S configuration for the compound.