146085-66-7

Basic information

• Product Name: N-(p-methylbenzyl)-O-benzyl-N-nitrosohydroxylamine
• Synonyms: N-(p-methylbenzyl)-O-benzyl-N-nitrosohydroxylamine
• CAS NO: 146085-66-7
• Molecular Weight: 256.304
• Mol File: 146085-66-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(p-methylbenzyl)-O-benzyl-N-nitrosohydroxylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(p-methylbenzyl)-O-benzyl-N-nitrosohydroxylamine(146085-66-7)
• EPA Substance Registry System: N-(p-methylbenzyl)-O-benzyl-N-nitrosohydroxylamine(146085-66-7)

Safety Data

• Hazardous Substances Data: 146085-66-7(Hazardous Substances Data)

Upstream product

• 140451-62-3 O-benzyl oxime of 4-methylbenzaldehyde 
• 146085-60-1 N-(p-methylbenzyl)-O-benzylhydroxylamine hydrochloride 

Downstream Products

• 146085-61-2 N-benzyl-O-(p-methylbenzyl)hydroxylamine hydrochloride 
• 38936-61-7 2-((4-methylbenzyl)oxy)isoindoline-1,3-dione 
• 146085-59-8 O-(p-methylbenzyl)benzaldoxime 
• 86396-64-7 N-nitroso-N-benzyl-O-(p-methylbenzyl)hydroxylamine 
• 83670-44-4 O-(p-methylbenzyl)hydroxylamine 
• 16814-17-8 N-(p-methylbenzyl)hydroxylamine 
• 104-87-0 4-methyl-benzaldehyde 
• 100-44-7 benzyl chloride 
• 104-82-5 4-Methylbenzyl chloride 
• 146085-60-1 N-(p-methylbenzyl)-O-benzylhydroxylamine hydrochloride 
• 2216-45-7 p-methylbenzyl alcohol acetate 

Relevant articles and documents

N-NITROSOHYDROXYLAMINES I. ACETOLYSIS AND ACID-CATALYZED HYDROLYSIS OF N,O-DIBENZYL-N-NITROSOHYDROXYLAMINES. REACTION WITH POTASSIUM t-BUTOXIDE

The major products of the hydrolysis of N,O-dibenzyl-N-nitrosohydroxylamines (3) are the denitrosated parent hydroxylamines (6); under more forcing conditions, products of the further hydrolysis of 6 are obtained.Acetolysis in acetic acid gives the benzyl acetates derived from both N- and O-substituents.With potassium tert-butoxide, the major path is abstraction of an O-benzyl hydrogen followed by fragmentation to the aldehyde and the benzyldiazotate ion.Possible mechanisms for the formation of the products are discussed.