146197-51-5Relevant articles and documents
A formal synthesis of crinipellin B based on the arene-alkene meta- photocycloaddition reaction
Wender, Paul A.,Dore, Timothy M.
, p. 8589 - 8592 (2007/10/03)
Starting from triethyl phosphonopropionate and 3-nitro-2-methylbenzoic acid, a formal synthesis of crinipellin B was achieved. The strategy draws on the use of a novel version of the arene-alkene meta-photocycloaddition reaction that proceeds with the generation of 4 rings and 4 quaternary stereocenters in one synthetic operation.