14629-52-8Relevant articles and documents
Hydrosilylation of epoxides catalyzed by a cationic η1- silane iridium(iii) complex
Park, Sehoon,Brookhart, Maurice
supporting information; experimental part, p. 3643 - 3645 (2011/05/04)
Cationic silane complex 2, catalyzes the hydrosilylation of epoxides and cyclic ethers to give the silyl-protected alcohols, regioselectively. A mechanistic study shows that the epoxide undergoes isomerization to the ketone, followed by hydrosilylation.