14629-96-0Relevant articles and documents
A First Palladium-Catalyzed Aryldegermylation of Styryltrimethylgermanes
Ikenaga, Kazutoshi,Matsumoto, Satoshi,Kikukawa, Kiyoshi,Matsuda, Tsutomu
, p. 185 - 188 (2007/10/02)
Both β-(E)- and β-(Z)-styryltrimethylgermanes easily reacted with arenediazonium tetrafluoroborates under palladium catalysis to give aryldegermylated products, (E)-PhCH=CHAr and Ph(Ar)C=CH2.On the other hand, the aryldegermylation of α-styrylgermane gave (E)-stilbene derivates with high stereo- and regioselectivities.