146509-65-1Relevant articles and documents
Process for preparation 2,6-dihydrobenzo[1:26, 4:5-6]-difuran dyes
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, (2008/06/13)
A process for the preparation of a polycyclic dye of the Formula (1): STR1 by reacting a substituted acetic acid of the Formula (2): STR2 with a compound of the Formula (3): STR3 and oxidation of the intermediate leuco compound to dehydrogenate the peripheral heterocyclic rings wherein Y is an optionally substituted aromatic or heteroaromatic radical; Ring A is unsubstituted or is substituted by from one to five groups; Z is --NR1 R2 ; R1 and R2 are each independently H or are independently selected from optionally substituted alkyl, alkenyl, cycloalkyl, aralkyl, aryl and heteroaryl; or R1 and R2 together with the nitrogen atom to which they are attached form a heterocyclic ring; or R1 and R2 each independently together with the nitrogen to which they are attached and the adjacent carbon atom of Ring B form a heterocyclic ring; and X1 and X2 are each independently selected from H, halogen, optionally substituted alkyl, optionally substituted aryl, optionally substituted heteroaryl, cyano, carbamoyl, sulphamoyl, carboxylic acid and carboxylic acid ester, a process for the preparation of the substituted acetic acid of Formula (2) and certain novel substituted acetic acids of Formula (2).