1467081-71-5Relevant articles and documents
Reaction of Lawesson's reagent with Mannich base hydrochlorides: Synthesis of novel 4H-1,3,2-oxathiaphosphorine-2-sulfide derivatives
Aouani, Iyadh,Touil, Soufiane
, p. 164 - 169 (2014/01/23)
In a simple and general protocol, the treatment of Mannich base hydrochlorides, derived from acyclic and cyclic ketones, with Lawesson's reagent, leads to novel 4H-1,3,2-oxathiaphosphorine derivatives in good yields. A possible reaction mechanism, involving a [4+2] cycloaddition, is proposed.